Document Type : Research Paper

Authors

1 Department of soil science, faculty of water and soil engineering,Gorgan University of Agricultural Sciences and Natural Resources

2 Dept. of Soil Science, Gorgan University of Agricultural Sciences and Natural Resources, Iran

3 Dept. of Soil Science, College of Agriculture, Isfahan University of Technology

4 Department of Soil Science, Gorgan University of Agricultural Sciences and Natural Resources

5 Institute of Geography, Cologne University, Germany

6 Institute for Crop Science and Resource Conservation-Soil Science, Bonn University, Germany

Abstract

Introduction The loess-paleosol sequences in Northern Iran are important archives that represent several cycles of Quaternary climate change and can be used to complete the information gap on loess between Europe and central Asia. Last interglacial soils derived from loess in northern Iran is represented by strongly developed Bt horizons of forest soils. In Golestan and Mazandaran area, soils under the forest are mainly classified as Alfisols or Luvisols. Interestingly, E horizons are generally not found in these soils. In the Caspian Lowlands, a pronounced precipitation gradient is reflected in mean annual precipitation rates decreasing from about 1850 mm at Bandar Anzali in the west to about 435 mm at Gonbad- e Kavoos in the east. The results of the loess climosequence in Northern Iran showed that with increasing precipitation, soil pH and calcium carbonate contents decrease, whereas soil organic carbon, clay content, and cation exchange capacity increase. For years, many efforts to quantify the soil properties led to the provision of indices of soil development. Among these indices are forms and ratios of iron, morphological, and micromorphological indices. Many studies have been carried out on the loess-paleosol sequences and modern loess soils in Northern Iran with focus on micromorphology, mineralogy, and dating but more investigation is needed with an emphasis on the forest soils with well-pronounced clay illuviation as a proxy for paleo-moisture. For this purpose, we used micromorphology and soil color indices to report the effects of precipitation gradient on the variability in the formation of soils under forest vegetation.
Materials and Methods The study area is located at the northern slopes of Alborz Mountain Ranges, covered with Caspian or Hyrcanian deciduous forests. Field sampling started in summer 2015. More than ten soil pedons with loess parent material were investigated based on former studies. Finally, six representative modern pedons were selected and dug in an east-west direction on loess deposits. The climate data shows that precipitation varies from 500 mm in Qapan (Pedon 1) to up to 800 mm in Neka. Physiochemical properties of soils were studied using standard methods. Thin section prepared for soil micromorphological studies were studied and interpreted based on Bullock et al. and Stoops guideline using a polarizing microscope. The micromorphological index of soil development (MISECA), suggested by Khormali et al (2003), was calculated. Also, color indices were calculated based on Hurst (1977), Torrent (1983), and Alexander (1985) by using the Munsell color chart. In all color indices, Munsell color hue converts to a single number.
Results and Discussion The results showed that the downward decalcification and the subsequent clay illuviation were the main criteria influencing the assessment of soil development in this study. So, all of the soils host argillic and calcic horizons and are classified as Alfisols and Mollisols. Micromorphological studies confirmed the morphology studies in the field and the results of physico-chemical analyses. MISECA index showed pedological changes in different pedons in the studied areas. A significant positive relationship between climate gradient (increasing rainfall) and MISECA index was found. The area and thickness of clay coatings show an increasing trend with rainfall. Occurrence and preservation of clay coatings are more pronounced in more humid regions with illite and vermiculite as the dominant clay minerals. These minerals reduce the shrink/swell potential and increase the number of clay coatings present. In Argillic horizons of all pedons, except Toshan, dominant b-fabric is speckled due to carbonate leaching, while in Toshan, it is striated b-fabric. In calcite horizon, b-fabric is crystallitic. The correlation of various forms of iron with three color indices of Hurst, Torrent, and Alexander showed that Torrent and Alexander indices were better than the other one for the study area. Moreover, there was a good correlation between MISECA and Torrent color index.
Conclusion The results showed that the soil evolution in the studied areas is strongly influenced by soil formation factors, especially in a climate which shows a change in the micromorphological characteristics of soils. With increasing the rainfall from the east to the west in this gradient, the amount and thickness of clay coating, as well as secondary calcium carbonate accumulation, change significantly. In addition, the micromorphological and color indices of soil evolution can be used as two indicators for assessing the effects of rainfall gradient on soil formation in northern Iran. On the other hand, knowledge of the development of modern loess-derived soils could help to better understand the paleoenvironment.

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  1. Ajami, M., Heidari, A., Khormali, F., Gorji, M., and Ayoubi, Sh. 2018. Effects of environmental factors on classification of loessderived soils and clay minerals variations, northern Iran. Journal of Mountain Science, 15(5): 976-991.
  2. Alexander, E.B. 1985. Estimating relative ages from iron-oxide/total-iron ratios of soils in the western Po Valley, Italy: a discussion. Geoderma, 35: 257-259.
  3. Alonso-Zarza, A.M. 2018. Study of a modern calcrete forming in Guadalajara, Central Spain: An analogue for ancient root calcretes. Sedimentary Geology, 373: 180-190.
  4. Bajno´czi, B., and Kova´cs-Kis, V. 2006. Origin of pedogenic needle-fiber calcite revealed by micromorphology and stable isotope composition - a case study of a Quaternary paleosol from Hungary. Geochemistry, 66: 203-212.
  5. Becze- Deak, J., Langhor, R., and Verrechia, E.P. 1997. Small scale secondary CaCO3 accumulations in selected section of the European loess belt. Geoderma, 76: 221-252.
  6. Chapman, H.D. 1965. Cation exchange capacity. In: Black, C.A. (Ed.), Methods of Soil Analysis Part 2. American Society of Agronomy, Madison, WI, pp. 891–901.
  7. Fernandez, R.N., Schulze, D.G., Coffin, D.L., and Vanssoyoc, G.E. 1988. Color, organic matter, and pesticide adsorption relationships in a soil-landscape. Soil Science Society of American Journal, 52: 1023-1026.
  8. Fitzpatrick, E.A. 1993. Soil microscopy and micromorphology. John Wiley and Sons Pub., Chichester Country.
  9. Frechen, M., Kehl, M., Rolf, C., Sarvati, R., and Skowronek, A. 2009. Loess chronology of the Caspian Lowland in Northern Iran. Quaternary International, 128: 220–233.
  10. Gee, G.W., and Bauder, J.W. 1986. Particle-size analysis. In: Klute, A. (Ed.), Methods of Soil Analysis. Part 1, Physical and Mineralogical Methods, second ed. Agronomy, Vol. 9, pp. 383–411.
  11. Ghergherechi, S., Khormali, F., Mahmoudi, Sh., and Ayoubi, S. 2011. Micromorphology of argillic horizon developed on loess derived soils in humid and sub humid regions of South Western Golestan Province. Iranian Journal of Soil and Water Research, 2: 237-350. (In Persian with English Abstract)
  12. Gunal, H., and Ransom, M.D. 2006. Genesis and micromorphology of loess-derived soils from central Kansas. Catena, 65: 222-236.
  13. Hosseini, S.S., Esfandiarpour Borujeni, I., Farpoor, M.H., and Karimi, A.R. 2015. Comparsion of different soil development indices along Kerman-Baft transect. Journal of Soil Management and Sustainable Production, 5(2): 1-24.
  14. Hurst, V.J. 1977. Visual estimation of iron in saprolite. Geological Society of America Bulletin, 88:174-176.
  15. Kehl, M., Sarvati, R., Ahmadi, H., Frechen, M., and Skowronek, A. 2005. Loess paleosol-sequences along a climatic gradient in Northern Iran. Eiszeitalter und Gegenwart, 55: 149–173.
  16. Kemp R.A., and Zárate M.A. 2000. Pliocene pedosedimentary cycles in the southern Pampas, Argentina. Sedimentology, 47: 3-14.
  17. Khan, F.A., and Fenton, T.E. 1996. Secondary iron and manganese distributions and aquic conditions in a Mollisol catena of Central Iowa. Soil Science Socity American Journal, 60: 546-551.
  18. Khormali, F., Ajami, M., and Ayoubi, S. 2006. Genesis and micromorphology of soils with loess parent material as affected by deforestation in a hillslope of Golestan province, Iran. In: 18th International Soil Meeting (ISM) on Soil Sustaining Life on Earth, Managing Soil and Technology, May 22-26, pp. 149-151.
  19. Khormali, F., Abtahi, A., and Stoops, G. 2006. Micromorphology of calcitic features in highly calcareous soils of Fars Province, Southern Iran. Geoderma, 132: 31-46.
  20. Khormali, F., and Shamsi, S. 2009. Micromorphology and quality attributes of the loess derived soils affected by land use change: A case study in Ghapan watershed, Northern Iran. Journal of Mountain Science, 6: 197–204.
  21. Khormali, F., Ghergherechi, S., Kehl, M., and Ayoubi, S. 2012. Soil formation in loess-derived soils along a subhumid to humid climate gradient, Northeastern Iran. Geoderma, 179–180: 113-122.
  22. Khormali, F., Abtahi, A., Mahmoodi, S., and Stoops, G. 2003. Argillic horizon development in calcareous soils of arid and semi-arid regions of southern Iran. Catena, 53: 273-301.
  23. Kooistra, M. J. 1978. Soil development in recent marine sediments of the intertidal zone in the Oosterschelde, the Netherlands: a soil micromorphological approach. Wageningen: Stichting voor Bodemkartering Wageningen. pp: 1-184.
  24. Mckeague, J.A., and Day, J.H. 1966. Dithionite and oxalate extractable Fe and Al as aids in differentiating various classes of soil. Canadian Journal of Soil Science, 46:13- 22.
  25. Mehra, O.P., and Jackson, M.L. 1960. Iron oxide removal from soils and clays by a dithionitecitrate system buffered with sodium bicarbonate. Clays and Clay Minerals, 5: 317–327.
  26. Milliere, L., Hasinger, O., Bindschedler, S., Cailleau, G., Spangenberg, J.E., and Verrecchia. E.P. 2011. Stable carbon and oxygen isotope signatures of pedogenic needle fibre calcite. Geoderma, 161: 74–87.
  27. Nelson, D.W., and Sommers, L.E. 1982. Total carbon, organic carbon, and organic matter. In: Page, A.L. (Ed.), Methods of Soil Analysis, Part 2. American Society of Agronomy, Madison.WI, pp: 539–579.
  28. Nettleton, W.D., Olsen, C.G., and Wysocki, D.A. 2000. Paleosol classification: Problems and solutions. Catena, 41: 61-92.
  29. Owliaie, H.R. 2012a. Micromorphology of calcitic features in calcareous soils of Kohgilouye Province, Southwestern Iran. Journal of Agricultural Science and Technology, 14: 225-239.
  30. Owliaie, H.R. 2012b. Study of genesis and micromorphology of soils along a catena in Yasouj Region (Case Study: Dasht-e-roum Plain). Journal of Water and Soil, 26(2): 427-439. (In Persian with English Abstract)
  31. Quénard, L., Samouëlian, A., Laroche, B., and Cornu, S. 2011. Lessivage as a major process of soil formation: a revisitation of existing data. Geoderma, 167–168: 135– 147.
  32. Salinity Laboratory Staff. 1954. Diagnosis and improvement of saline and alkali soils. United States Department of Agriculture Handbook No. 60 Washington, DC.
  33. Sauzet, O., Cammas, C., Barbillon, P., Étienne, M.P., and Montagne, D. 2016. Illuviation intensity and land use change: Quantification via micromorphological analysis. Geoderma, 266: 46-57.
  34. Soil survey staff. 2014. Keys to soil taxonomy. U.S. Department of Agriculture, Natural Resources Conservation Service.
  35. Stoops, G. 2003. Guidelines for the Analysis and Description of Soil and Regolith Thin Sections. Soil Science Society of America, Madison, WI.
  36. Stoops, G., Marcelino, V., and Mees, F. 2010. Interpretation of Micromorphological Features of Soils and Regoliths, first ed. Elsevier Science, p. 752.
  37. Tazikeh, H., Khormali F., Amini A., Barani Motlagh M., and Ayoubi Sh. 2017. Soilparent material relationship in a mountainous arid area of Kopet Dagh basin, North East Iran. Catena, 152: 252-267.
  38. Torrent, J., Schwertmann, U., Fechter, H., and Alferez, F. 1983. Quantitative relationships between soil color and hematite content. Soil Science, 136: 354-358.
  39. Torrent, J., Barrón, V., Liu, Q.S., 2006. Magnetic enhancement is linked to and precedes hematite formation in aerobic soil. Geophysical Research Letters, 33, L02401.
  40. Vlaminck, S., Kehl, M., Lauer, T., Shahriari, A., Sharifi, J., Eckmeier, E., Lehndorff, E., Khormali, F., and Frechen, M. 2016. Loess-soil sequence at Toshan (Northern Iran): Insights into late Pleistocene climate change. Quaternary International, 399: 122-135.
  41. World reference base for soil resources (WRB). 2014. Food and Agriculture Organization of the United Nations, Rome.
  42. Zarate, M., Kemp, R.A., Espinosa, M., and Ferrero, L. 2000. Pedosedimentary and paleoenvironmental significance of a Holocene alluvial sequence in the southern Pampas, Argentina. The Holocene, 10: 481-488.
  43. Zamanian, K., Pustovoytov, K., and Kuzyakov, Y. 2016. Pedogenic carbonates: forms and formation processes. Earth-Science Reviews, 157: 1-17.
  44. Zeraat Pishe, M. 2010. Carbon stock and mineral factors controlling soil organic carbon in a climosequence, Golestan province. M.Sc Thesis, Gorgan University of Agriculture Sciences and Natural Resources, 135pp. (In Persian with English Abstract)