Document Type : Research Paper

Authors

1 Professor, Department of Geology and Dust Research Center, Shahid Chamran University of Ahvaz, Iran.

2 Ph. D Student, Department of Geology, Faculty of Earth Sciences, Shahid Chamran University, Ahvaz, Iran

3 Ph. D Student of Environmental Geology, Azad University, Science and Research Branch, Ahvaz and Khuzestan Environmental Protection Office

4 Ms. C Student, Department of Geology, Faculty of Earth Sciences, Shahid Chamran University, Ahvaz, Iran

Abstract

Introduction Dust storms or sand storms are some of the meteorological phenomena that demonstrate differences with one another terminologically. These kinds of storms usually occur under arid and semiarid areas in circumstances which the blowing speed of a gale is higher than the erosion threshold. In other words, Dust and sand storms are persistent problems in the Middle East Region. The regional dust storms have bad effects on the health of human life which can cause asthma, bronchitis and lung diseases, due to their carrying micro-organisms (such as bacteria, fungi, spores, viruses and pollen) and their sharp edged particles. Several studies researches have shown that microorganisms mobilized into the atmosphere along with desert soils are capable of surviving long-range transport on a global scale. Dust-borne microorganisms in particular can.
directly impact human health via pathogenesis,exposure of sensitive individuals to cellular components. The chemical components of dust are affecting the microbial life besides the precipitation, wind direction, time of day, season and atmosphere inversion conditions, all affecting the survival of total bacteria communities associated with dust particles, and the microbes are capable of surviving long distance transport. Dust storms have become a major environmental concern during the last decades in the oil- and gas-rich Khuzestan province in the southwestern Iran. Dust storms frequently occur in Khuzestan mainly during summer, and intense dust storms are particularly associated with easterly-blowing winds. High frequency (10-15%) and health outcomes of local dust storms in Khuzestan province, requires an extensive study on various factors of local storms such as heavy metal geochemistry and its environmental consequences are very important. In this paper, we present an overview of the geochemical and geo-environmental characteristics of dust storms in Khuzestan.
Materials and Methods Information about dust storms of source and coverage was obtained from meteorological stations in Khuzestan province. In this study, airborne dust samples were collected to obtain TSP and PM10 by using the high-volume air (HVA) sampler model TCR. The geochemistry of airborne dust samples was analyzed at the Actlabs (Canada). The concentration of V, Co, Ni, As, Cd, Pb and Zn was determined in Actlab, Canada, using ICP-MS method.
Results and Discussion The obtained results showed that Pb concentration in TSP samples ranges between 8.11 and 197 ppm with an average and median value of 23.6 and 11.15 ppm, respectively. The zinc content in PM10 samples, ranges between 4670 and 5000 ppm. Also, Ni has high concentration that ranges between 5.8 - 43.2 in PM10 samples. Lowest concentration of Cobalt is present in PM10 samples that ranges between 0.6 and 4.7 ppm. Vanadium has the highest concentration in Ahvaz samples. Also, PM10 samples include higher Arsenic concentration than TSP samples. Finally, Cd has the lowest concentration in all of the  studied heavy metals with the mean value of 0.12 ppm. Positive correlation (0.9) between Cu with V, Co and Ni shows probably a similar source for these elements. Investigation of heavy metals concentration in various dust storms confirms that arsenic has a higher concentration in local storms. Seasonal studies show that V, Co and As have high concentrations in warm periods and Pb has the highest frequency in the cold season, in Khuzestan province. Based on the study of Contamination Factor (CF), the mean CF of heavy metals was in the order Pb > Zn > Cd >As > Ni > Co> V. Also, Degree of Contamination (DC) factor of the studied heavy metals in PM10 samples with mean value of 40 ppm is higher than TSP samples with average value of 10 ppm. In relation to the Enrichment Factor (EF) for V, Co, Ni, As, Cd, Pb and Zn, the EF mean of these metals was in the order Cd > Zn > Ni > Pb > As > V > Co. The highest Arsenic enrichment factor can be seen in PM10 samples.
Conclusion The obtained results from calculation of Integrated Pollution Index (IPI) in PM10 samples showed that, V, Co, Ni and Pb are non-polluted. Also, Cadmium, Arsenic and Zinc showed a low, medium and high levels of pollution, respectively. Furthermore, based on IPI data in TSP samples, Co, As and V were non-pollution and  Pb, Ni, Zn showed low level of contamination. Finally, Cadmium in TSP samples in dicated a high level of Integrated Pollution Index.

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Main Subjects

  1. AbdUlRahman, I.Q., Kusag, A.D., and Hassein, A.T. 2013. Measuring the concentrations of some heavy elements indoor and outdoor during dust storms in Anbar province in Iraq. International Journal of Emerging Technology and Advanced Engineering, 3: 578-582.
  2. Aditi Kulshrestha, P., Satsangi, G., Masih, J., and Taneja, A. 2009. Metal concentration of PM2.5 and PM10 particles and seasonal variations in urban and rural environment of Agra, India. Science of the Total Environment, 407: 6196–6204.
  3. Ahmed, F., and Ishiga, H. 2006. Trace metal concentrations in street dusts of Dhaka city, Bangladesh. Atmospheric Environment, 40: 3835-3844.
  4. Balakrishna, G., Pervez, S., and Bisht, D.S. 2011. Source apportionment of arsenic in atmospheric dust fall out in an urban residential area, Raipur, Central India. Atmospheric Chemistry and Physics, 11: 5141-5151.
  5. Crosbie, E., Sorooshian, A., Monfared, N.A., Shingler, T., and Esmaili, O. 2014. A multiyear aerosol characterization for the greater Tehran area using satellite, surface, and modeling data. Atmosphere, 5: 178–197.
  6. Engelstaedter, S., Kohfeld, K.E., Tegen, I., and Harrisonand, S. P. 2003. Controls of dust emissions by vegetation and topographic depressions: an evaluation using dust storm frequency data. Geophysical Research Letters, 30: 1294.
  7. Fazeli, M. S., Moosavi, M.H., Pournia, M., and Zergani, Z. J. 2009. Metals Distribution in Topsoils around Industrial Town of Ahwaz, Iran. Journal of Applied Sciences, 9: 1121-1127.
  8. Fiori, C.D.S., Rodrigues A.P.D.C., Santelli, R.E., Cordeiro, R.C., Carvalheira, R. G., Araujo, P.C., Castilhos, Z.C., and Bidone, E.D. 2013. Ecological risk index for aquatic pollution control: a case study of coastal water bodies from the Rio de Janeiro State, southeastern Brazil. Geochemical Brasiliensis, 27: 24-36.
  9. Ginoux, P., Prospero, J. M., Gill, T.E., Hsu, N.C., and Zhao, M. 2012. Global scale attribution of anthropogenic and natural dust sources and their emission rates based on MODIS Deep Blue aerosol products. Reviews of Geophysics, 50:1-36
  10. Hsu, S.C., Liu, S.C., Lin, C.Y., Hsu, R.T., Huang, Y.T., and Chen, Y.W. 2004. Metal Compositions of PM10 and PM2.5 Aerosols in Taipei during spring, 2002. Terrestrial, Atmospheric and Oceanic Sciences, 15: 925-948.
  11. Indoitu, R., Orlovsky, L., Orlovsky, N. 2012. Dust storms in Central Asia: Spatial and temporal variations. Journal of Arid Environments, 85: 62-70.
  12. Jickells, T.D., An, Z.S., Andersen, K.K., Baker, A.R., Bergametti, G., Brooks, N., Cao, J.J., Boyd, P.W., Duce, R.A., Hunter, K.A., Kawahata, H., Kubilay, N., laRoche, J., Liss, P. S., Mahowald, N., Prospero, J.M., Ridgwell, A.J., Tegen, I., and Torres, R. 2005. Global iron connections between desert dust, ocean biogeochemistry, and climate. Science, 308: 67–71.
  13. Krasnov, H., Katra, I., Friger, M. 2016. Increase in dust storm related PM10 concentrations: A time series analysis of 2001-2015. Environmental Pollution, 213: 36-42.
  14. Kumar, S., Kumar, S., Kaskaoutis, D.G., Singh, R.P., Singh, R.K., Mishra, A. K., Srivastava, M.K., and Singh, A.K. 2015. Meteorological, atmospheric and climatic perturbations during major dust storms over Indo-Gangetic Basin Aeolian Research 17: 15–31.
  15. Lee, H., Honda, Y., Li, Y.H., Guo, Y.L., Hashizume, M., and Kim, H. 2014. Effect of Asian dust storms on mortality in three Asian cities. Atmospheric Environment, 89: 309-317.
  16. Lee, J.J., and Kim, C.H. 2012. Roles of surface wind, NDVI and snow cover in the recent changes in Asian dust storm occurrence frequency. Atmospheric Environment, 59: 366-375.
  17. Lu, X., Wang, l., Lei, K., Huang, J., and Zhai, Y. 2009. Contamination assessment of copper, lead, zinc, manganese and nickel in street dust of Baoji, NW China. Journal of Hazardous Materials, 161: 1058-1062.
  18. Lu, X., Wang, L., Li, L.Y., Lei, K., Huang, L., and Kang, D. 2010. Multivariate statistical analysis of heavy metals in street dust of Baoji, NW China. Journal of Hazardous Materials, 173: 744-749.
  19. Maghrabi, A.H., and Al-Dosari, A. F. 2015. Effects on surface meteorological parameters and radiation levels of a heavy dust storm occurred in Central Arabian Peninsula. Atmospheric Research, 182: 30–35.
  20. Meena, M., Singh, B., Chandrawat, U. and Rani, A. 2014. Seasonal Variations and Sources of Heavy Metals in Free Fall Dust in an Industrial City of Western India. Iranica Journal of Energy and Environment, 5: 160-166.
  21. Mohamed, T.A., Mohamed, A.K.M., Rabeiy, R., and Ghandour, M.A. 2013. A Study of Heavy Metals in the Dust Fall around Assiut Fertilizer Plant. Journal of Environmental Protection, 4: 1488-1494.
  22. Morton-Bermea, O., Hernández-Á lvarez, E., Lozano, R., Guzmań-Morales, J., and Martínez, G. 2008. Spatial distribution of heavy metals in top soils around the industrial facilities of Cromatos de México, Tultitlan Mexico. Bulletin of Environmental Contamination and Toxicology, 85:520–524.
  23. Pirshaheb, M., Zinatizadeh, A., Khosravi, T., Atafar, Z., and Dezfulinezhad, S. 2014. Natural Airborne Dust and Heavy Metals: A Case Study for Kermanshah, Western Iran (2005–2011). Iranian Journal of Public Health, 43: 460–470.
  24. Prospero, J., Ginoux, P., Torres, O., Nicholson, Sh., and Gill, T. 2002. Environmental characterization of global sources of atmospheric soil dust identified with the Nimbus 7 Total Ozone Mapping Spectrometer (TOMS) absorbing aerosol product. Reviews of Geophysics, 40: 1-31.
  25. Rajabi, M., and Souri, B. 2015. Evaluation of heavy metals among dust fall particles of Sanandaj, Khorramabad and Andimeshk cities in western Iran. Iranian Journal of Health and Environment, 8: 2-11(in Persian with English abstract)
  26. Reheis, M.C., Budahn, J.R., and Lamothe, P.J., 2002. Geochemical evidence for diversity of dust sources in the southwestern United States. Geochimica et Cosmochimica Acta, 66: 1569-1587.
  27. Talebi, S.M., and Ghanani, T. 2008. Level of PM10 and its chemical composition in the Atmosphere of the city of Isfahan. Iranian Journal of Chemical Engineering, 5: 62-65.
  28. Tamrakar, C.S., and Shakya, P.R. 2011. Assessment of heavy metals in street dust in Kathmandu Metropolitan City and their possible impacts on the environment. Pakistan Journal of Analytical and Environmental Chemistry, 12: 32-41.
  29. Taylor, S.T., and Mclennan, S.M. 1995. The geochemical evolution of the continental crust. Reviews of Geophysics, 33: 611- 627.
  30. Ubwa, S.T., Abah, J., Ada, C.A., and Alechenu, E. 2013. Levels of some heavy metals contamination of street dust in the industrial and high traffic density areas of Jos Metropoli. Journal of Biodiversity and Environmental Sciences, 3: 13-21.
  31. Wang, R., Liua, B., Li, H., Zou, X., Wang, J., Liu, W., Cheng, H., Kang, L., and Zhang, C. 2017. Variation of strong dust storm events in Northern China during 1978–2007. Atmospheric Research, 183: 166–172.
  32. Wang, Y.C., and Lin, Y.K. 2015. Mortality associated with particulate concentration and Asian dust storms in Metropolitan Taipei. Atmospheric Environment, 117: 32-40.
  33. Wei, B., Jiang, F., Li, X., and Mu, S. 2010. Heavy metal induced ecological risk in the city of Urumqi, NW China. Environmental Monitoring and Assessment, 160: 33–45.
  34. WMO. 2007. WMO Sand and Dust Storm Warning Advisory and Assessment System (SDS-WAS).
  35. Yongming, H., Peixuan, D., Junji, C., and Posmentier, E.S. 2006. Multivariate analysis of heavy metal contamination in urban dusts of Xi'an, Central China. Science of the Total Environment, 355: 176-186.
  36. Zarasvandi, A.R, Carranza, E.J.M., Moore, F., and Rastmanesh, F. 2011. Spatio - temporal occurrences and mineralogical-geochemical characteristics of airborne dusts in Khuzestan Province (southwestern Iran). Journal of Geochemical Exploration, 111: 138-151.