Soil Chemistry and Pollution
Hadi Habiby; Alireza Movahedi; Mojtaba Khoshravesh; Alireza Saberi
Abstract
Introduction Increasing the yield and, consequently, increasing the concentration of macro and micro nutrients in the plant is one of the important aspects of agriculture. The improvement of the quality and quantity of some elements, such as potassium, zinc, and iron in the soil can cause an increase ...
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Introduction Increasing the yield and, consequently, increasing the concentration of macro and micro nutrients in the plant is one of the important aspects of agriculture. The improvement of the quality and quantity of some elements, such as potassium, zinc, and iron in the soil can cause an increase in the yield of the crop and the concentration of these elements in plant tissues. The increase in the concentration of these elements in plants can be effective in the health of livestock and consequently the health of humans. One of the new approaches that can be used in this field is the use of magnetic water. Magnetic water is obtained by passing water from a magnetic field. An externally applied magnetic field causes changes in the atomic, molecular, and electronic structure of the treated water, such as changes to its solidifying and boiling points, viscosity and the dielectric constant, the formation of clustering structures from linear and ring hydrogen-bound chains of molecules, the magnetic interaction between these clustering structures, and increasing the polarization effects of water molecules. The biological effects of magnetic field or electromagnetic field treatments depend on the strength and exposure period of water conditioning, in particular, the ion content, quality, and the volume of water. Materials and Methods For this purpose, a field experiment was conducted in a factorial arrangement with two main treatments, adding and without adding potassium and zinc fertilizers, and five sub-treatments (magnetic field strengths, including a 0.4 Electromagnetic Coil (EC), 0.3 magnet, 0.3 EC, 0.1 EC, and the control treatment) in four replications at Research Station of Goran University of Agricultural and Natural Resources. The size of each experimental plot was 2 m × 2.5 m. Corn was planted in each plot with the distances of 15 cm from each other and rows with distances of 70 cm from each other. An electromagnetic coil and a permanent magnet were used to create a magnetic field. Water was passed from the middle of this magnetic field through a hose and the plots were irrigated with this magnetic water. The irrigation was conducted based on soil moisture content and continued until the harvest and drying of the plants. Soil and plant samples were taken at two flowering and harvesting stages and were transferred to the laboratory for analyzation. Concentrations of Zn and Fe in the soil and plant tissues were measured. Statistical analysis was performed using the SAS software. Results and Discussion The results of this study showed that all the plots that were irrigated by magnetic water had corn plants with greater height and more yield was obtained than the control treatments. This could be due to the ease of absorbing water from the soil. Magnetic water has lower surface tension than untreated water, so the plant needs less force to absorb water from soil particles. Also, the plants that were irrigated by magnetic water had higher concentrations (P <0.01) of elements such as zinc and iron in their cobs. Magnetic water can increase the availability of the elements in the soil. So, more concentration of elements can be absorbed by the roots and transferred to the aerial parts of the plants. Among the magnetic water treatments, 0.4 Tesla strength treatment had the highest effect on the yield and corn height, as well as zinc and iron concentration in cobs (P <0.01). Higher strengths of the magnetic field (0.4 T) had more effect on the availability of elements in the soil and their absorption by the plants. The yield of corn in 0.4 EC, 0.3 M, 0.3 EC, and 0.1 EC treatments that potassium and zinc fertilizers were added to them increased as compared to the control. So, increasing the strength of the magnetic field had more effects on some soil properties. The treatments that K and Zn fertilizers were added to them had more yield than other treatments that these fertilizers were not added to them. This could be attributed to the fact that magnetic water has increased the solubility of K and Zn fertilizers. In fact, magnetic water has been able to increase the uptake of Zn from the soil. Conclusion These results indicate that the magnetization of water can be used as an appropriate approach to increase the quantity and quality of product yield and the concentration of the elements in the crops.
Plant Nutrition, Soil Fertility and Fertilizers
Yaser Azimzadeh; Nosratollah Najafi; Adel Reyhanitabar; Shahin Oustan; Alireza Khataee
Abstract
Introduction Phosphorus (P) is an essential element for living organisms. Discharging P from various sources, such as industrial wastewater and agricultural waters, into surface water causes eutrophication and undermines the balance of aquatic ecosystems and imposes many costs due to water quality degradation. ...
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Introduction Phosphorus (P) is an essential element for living organisms. Discharging P from various sources, such as industrial wastewater and agricultural waters, into surface water causes eutrophication and undermines the balance of aquatic ecosystems and imposes many costs due to water quality degradation. In addition, mineral resources of P-fertilizers in the world are unrecoverable and are coming to an end. Therefore, it is very important to develop adsorbents to remove P from contaminated water and then be used as P-fertilizer for surmounting the eutrophication and P-fertilizer exhausting challenges. In the last few years, biochar and hydrochar have been considered as low-cost porous eco-friendly adsorbents with a high surface area and easy to produce and use. Biochar and hydrochar are carbonaceous solids that are produced from the carbonization of biomasses and could be used as adsorbents and soil amendments. However, because of their high negative charge and very low ability to absorb anions, especially phosphate, they cannot be used as phosphate adsorbents. In recent years, several methods have been introduced to change the surface of biochar and hydrochar to increase their anion adsorption capacity. In this respect, the successful results of the production and the use of engineered biochars, such as layered double hydroxides (LDHs) functionalized biochar (LDH-biochar) and LDH-hydrochar composites have been provided. Layered double hydroxides (LDHs) are brucite-like compounds with a large specific surface area, high positive charge, and exchangeable interlayer anions. LDHs functionalized biochar and hydrochar composites are environmentally friendly adsorbents for the removal of phosphate from aqueous solutions. Also, P-loaded LDH-biochar and LDH-hydrochar composites have the potential application as a P-fertilizer. These composites may increase soil available-P through the slow release of P and can improve soil properties and fertility due to the presence of the biochar and hydrochar in their structure. So, the P-loaded LDH-biochar and LDH-hydrochar may affect the availability of soil nutrients and plant growth. Nitrogen (N), P, and potassium (K) are the macronutrients that have a direct and great influence on plants growth. Therefore, the aims of this study were: (I) producing LDH-biochar and LDH- hydrochar composites and loading them with phosphate. (II) Investigating the effects of the biochar, hydrochar, LDH, LDH-biochar, LDH-hydrochar, the P-loaded LDH-biochar (LDH-biochar-P), and LDH-hydrochar (LDH-hydrochar-P) on dry matter and concentrations of P, N, and K in corn shoot and root. Materials and Methods Biochar was produced from applewood feedstock through slow pyrolysis at 600 ºC for 1 h under Argon flow conditions. Hydrochar was produced through hydrothermal carbonization of the applewood feedstock at 180 ºC and 11 bars pressure for 12 h. Then by precipitation of LDH particles on the biochar and hydrochar surfaces, LDH-biochar and LDH-hydrochar composites were prepared. The LDH particles were synthesized via a combined fast co-precipitation and hydrothermal treatment route. Each gram of LDH-biochar and LDH-hydrochar composites was loaded with 51 and 47 mg P, respectively. Then using a factorial experiment on the basis of completely randomized design with three replications, the effects of biochar, hydrochar, LDH, LDH-biochar, LDH-hydrochar, LDH-biochar-P, and LDH-hydrochar-P were studied in presence and absence of monocalcium phosphate fertilizer on corn dry matter and concentrations of N, P, and K in corn shoot and concentrations of P and K in corn root. Results and Discussion The results showed that the biochar had a higher yield and ash percentage, pH and electrical conductivity (EC) as compared with the hydrochar. The concentrations of all studied nutrients in the biochar, except for N, were greater than those of hydrochar and biomass. The P, K, Na, Fe, Mn, and Zn concentrations in biochar and hydrochar were significantly greater than the initial biomass. The application of P-fertilizer increased root and shoot dry matters in all treatments, except for LDH-biochar-P and LDH-hydrochar-P treatments. Biochar and hydrochar had no significant effects on root and shoot dry matter in non-P-fertilized treatments and had no significant effects on P and K concentrations of corn root and shoot. However, biochar and hydrochar increased shoot dry matter in P-fertilized treatments. The highest root and shoot dry matters, P concentrations of root and shoot, and N concentration of shoot were obtained in the presence of the LDH-biochar-P and LDH-hydrochar-P, and the lowest root and shoot dry matters of corn were observed in the presence of the LDH. Application of P-fertilizer increased P concentrations of corn root and shoot in the presence of the LDH-biochar and LDH-hydrochar but decreased the K concentration of root in biochar, LDH-biochar and no amendment treatments and had no significant effects on N and K concentrations in the shoot. The application of P-fertilizer decreased P translocation factor in presence of the LDH-biochar and LDH-hydrochar and had no significant effect on P translocation factor in all other treatments. Using P-fertilizer had no significant effect on K translocation factor in all treatments. Biochar, hydrochar, LDH, LDH-biochar, and LDH-hydrochar had no significant effects on P and K translocation factors. The translocation factor of P was greater than 1 in all treatments, except for the LDH-biochar-P and LDH-hydrochar-P treatments. Also, the translocation factor of K was greater than that of P in all treatments. Conclusion Due to the structural similarities between biochar and hydrochar, LDH-biochar and LDH-hydrochar, and LDH-biochar-P and LDH-hydrochar-P, the root and shoot dry matter and concentrations of the studied elements in corn root and shoot were not significantly different between the biochar and hydrochar, LDH-biochar and LDH-hydrochar, and LDH-biochar-P and LDH-hydrochar-P treatments, respectively. P-fertilizer had synergistic relationships with biochar, hydrochar, LDH-biochar, and LDH-hydrochar but antagonistic relationships with LDH, LDH-biochar-P, and LDH-hydrochar-P composites in terms of dry matter and P concentrations in corn root and shoot. So, applications of the biochar, hydrochar, LDH-biochar, and LDH-hydrochar accompanied by P-fertilizer and the use of LDH-biochar-P and LDH-hydrochar-P without the application of P-fertilizer can be proposed for corn cultivation under similar conditions.
Plant Nutrition, Soil Fertility and Fertilizers
Soraya Taheri; abdolmajid ronaghi; Reza Ghasemi; Sedigheh Safarzadeh Shirazi
Abstract
Introduction Zinc deficiency is aggravated mainly in arid and semi-arid regions, due to low organic matter and soil moisture as well as high levels of pH and salinity. Maize which serves as staple food is sensitive to Zn deficiency. One of the mechanisms by which plants can adapt to nutrient deficient ...
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Introduction Zinc deficiency is aggravated mainly in arid and semi-arid regions, due to low organic matter and soil moisture as well as high levels of pH and salinity. Maize which serves as staple food is sensitive to Zn deficiency. One of the mechanisms by which plants can adapt to nutrient deficient soils has suggested producing and secreting organic substances, including aliphatic low molecular weight organic acids, into the rhizosphere for mobilization and uptake of nutrients. Under Zn deficiency, plants tend to modify rhizosphere in order to increase Zn phyto-availability. Zinc mobilization efficiency is dependent upon the amount and type of organic acids exuded by plant roots and physiochemical properties of soil. Therefore, the objectives of the present study were to investigate the influence of Zn deficiency on the shoot and root dry matter yields and the release rate of organic acids (malic, citric and acetic acids) commonly identified in root exudations of maize under Zn deficiency conditions. Materials and Methods Seeds of maize (SC703 and SC704) were surface sterilized and germinated in perlite moistened with distilled water. After seven days, the seedlings were transferred to 5-L containers with continuously aerated nutrient solution. Three Zn levels (0, 0.5, and 1 µM) were added to nutrient solutions. Ten weeks after maize emergence, intact plants were removed from nutrient solution and after two hours of the onset of the light period, roots samples were in opaque vessels containing fresh solution. The volume of collected solution was sufficient to submerge the whole maize roots samples. After three hours, roots samples were removed from the vessel and solution containing roots exudates was filtered and frozen at −20 ◦C until analysis of organic acids was performed. Organic acids were analyzed using high performance liquid chromatography (HPLC). Organic acids in the samples were identified by comparison with the retention time and absorption spectra of pure standards including malic, citric and acetic acid. The 1-cm washed root segments were placed in a beaker containing 10 mL deionized water and then root samples were immersed at 30◦C for three h, and then conductivity of solution was measured. The samples were boiled for 2 min, cooled to room temperature (25◦C) and then EC samples were measured. The electrolyte leakage was calculated as follows: Where C1 and C2 are electrical conductivities measured before and after boiling, respectively. Roots and shoot samples were ignited at 580 ◦C in an oven for 5 h and Zn concentration measured using atomic absorption spectroscopy (AAS). Results and Discussion In both genotypes shoot dry matter yield (SDMY) was significantly improved with increasing Zn concentration in nutrient solution. The highest value of SDMY was 19.8 g and belonged to Zn-adequacy level (1 µM) in SC703 genotype which had no significant difference with SC704 under the same treatments. There was no significant difference between Zn-sufficient and Zn-deficiency (0.5 µM) in SDMY in genotype SC703 whereas, a significant difference was observed at the same treatments in genotype SC704. The lowest value of SDMY was 14.7 g and belonged to the Zn-free treatment for genotype SC704. Root dry matter yield (RDMY) significantly increased with increasing Zn concentration in nutrient solution in both genotypes. The highest value of RDMY was 9.6 g and belonged to the treatment of Zn-adequacy for SC703 genotype which had no significant difference with SC704 genotype under the same treatment. The lowest value of RDMY was 4.8 g which was observed in Zn-free treatment for SC704 genotype. Results showed that the rate of organic acid exudation in both Maize genotypes decreased with increasing Zn levels in nutrient solution. The highest rate of MA exudation (6.6 mg /g root dry weight) was observed in Zn-free (Zn0) treatment in SC703 genotype and the lowest rate (1.98 mg g RDW-1) was observed in 1µm Zn treatment in SC704 genotype. Similar to MA, the rate of citric acid (CA) exudation rate significantly decreased with increasing Zn levels in nutrient solution. The highest rate of CA exudation rate was 1.06 (mg gRDW-1) and observed in Zn-free (Zn0) SC703 genotype. The lowest rate of CA was observed in 1µm Zn treatment SC704 genotype 0.2 (mg gRDW-1). The concentration of acetic acid (AA) was below the detection limit of HPLC in Zn sufficient and Zn deficiency treatments. However, AA concentrations in Zn-free were 0.66 and 0.25 (mg gRDW-1), respectively in SC703 and SC704 genotypes. The rate of MA was significantly higher than CA (4times) and AA (15 times higher). All organic acids exudation rate decreased with increasing Zn concentration in nutrient solution. There was a negative relationship between root and shoot Zn concentration with MA and CA exudation rate. MA, CA and AA exudation rate decreased as the concentration of Zn increased in root and shoot of maize. Roots membrane permeability decreased with increasing Zn concentration in nutrients solution which led to the reduction in root exudations. In both maize genotypes, the highest rate of root membrane permeability belonged to the Zn-free treatment (Zn0) which had the highest root exudation of organic acid and the lowest rate was observed in1µM Zn level with the lowest rate of organic acid exudation. It seems that Zn concentration in maize shoot control the release of root exudation of organic acids. In general, based on the results it can be concluded that SC703 genotype was more tolerant to Zn-deficiency compared to SC704 genotype partly due to the higher release rate of root organic acids. Further investigation is required to fully understand the physiology of organic acids release under Zn deficiency conditions.
Soil Biology, Biochemistry and Biotechnology
S. Shariati; H. Alikhani; A. Pourbabaei; F. Shariati
Volume 37, Issue 1 , September 2014, , Pages 93-107
Abstract
In order to determine the effect of plant growth promoting bacteria Pseudomonas fluorescens on yield and nutrient availability in corn some special materials like mesoporous silica nanoparticles, vermicompost, bentonite and a mixture of all were inoculated by the bacteria and preserved for six months. ...
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In order to determine the effect of plant growth promoting bacteria Pseudomonas fluorescens on yield and nutrient availability in corn some special materials like mesoporous silica nanoparticles, vermicompost, bentonite and a mixture of all were inoculated by the bacteria and preserved for six months. Soil and seeds were treated by the inoculants. The experiment was set up in a randomized complete block design with three replications. The treatments comprised of three inoculants and two fertilizers including diammonium phosphate, single super phosphate and control (without any phosphorus fertilizer). After 60 days of corn emergence, some plant growth indices and the concentration of some elements in plant shoots were measured. The results demonstrated that Pseudomonas fluorescens inoculant significantly increased phosphorus shoot content, total yield and chlorophyll by 74, 46 and 22.1%, respectively compared to the control treatment (P<0.05), but it did not show any significant difference with phosphorus fertilizer treatments (P>0.05). The vermicompost inoculants could significantly (P<0.05) increase zinc and iron contents of shoots by 114 and 53.6%, respectively in comparison to the control treatment. Orthogonal comparisons of the two methods of seed and soil inoculation showed the efficiency of seed inoculation on shoot phosphorus at 5% level, but no significant difference was observed between these two methods for other measured characteristics (P>0.05).
Mahmoud Ghaseminejad Raeini; Mohammad Sheikh Davoodi; Morteza Almasi; Houshang Bahrami; Eskandar Zand; Khalil Alamisaeid
Volume 36, Issue 2 , March 2014, , Pages 1-16
Abstract
In order to evaluate the effects of seed bed preparation, fertilization and weed control (after planting) methods on growth and corn yield in northern part of Khuzestan a field experiment was conducted as split blocks in a randomized complete block design with four replications during 2009 and 2010. ...
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In order to evaluate the effects of seed bed preparation, fertilization and weed control (after planting) methods on growth and corn yield in northern part of Khuzestan a field experiment was conducted as split blocks in a randomized complete block design with four replications during 2009 and 2010. Three seed bed preparations consisting of Makhar condition (wet seeding) + conventional tillage (plough + disk + leveler), makhar condition + reduced tillage (disk) and without makhar + reduced tillage were performed in horizontal plots. Two methods of fertilizing (Broadcast and Drill) as main factors and weed controlling methods (once using of field cultivator in four-leaf stage (20 cm height of plants), two times using rolling cultivator in four and seven-leaf stage (20, 40 cm height of plant), using two liters Nicosolforon herbicides when the plant produced 3 - 4 leaves, and checking treatments (weed free and weed infect) as the sub-factors were conducted in vertical plots. The results indicated that population and biomass dry weight of weeds were significantly (p< %5) affected by Makhar. Planting in without makhar soil, caused reduction in the population and weed weight (30% and 40%) in the 5th week. In all tillage methods, the effect of two times using rolling cultivator and chemical control on grain yield and biological yield was statistically similar. In fertilizer drill method, grain yield and biological yields, kernel in rows and rows in ear were significantly (P<%1) higher than broadcast method. The most grain and biological yield were obtained in combination of makhar condition and fertilizer drill (in treatment of makhar condition + reduced tillage, grain yield was 9003.25 kg/ha.). Two times using rolling cultivator reduced the population and weight of weeds significantly more than chemical control in farm with plenty of Bind weed. In all of the Broadcast fertilizer methods, chemical control treatment had more yield (16%), but in fertilizer drill method there was no significant difference between chemical and two times using of rolling cultivator treatments. It seems that in corn farms when broadcasting fertilizer method is used, the chemical control of weed due to higher yield (15%) is more effective; two cultivator weed control method is recommended if the distribution of fertilizer is used with drilling method. The highest grain yield (9183 kg/ha) was obtained from the combination of makhar, reduced tillage, fertilizer drilling method and two times using rolling cultivator.