Soil Chemistry and Pollution
Mina Hashemi Tazangi; Soheila Ebrahimi; Reza Ghorbani Nasrabadi; Seyed Alireza Movaheddi Naeeni
Abstract
Background and objectives: Hydrocarbons derived from petroleum and gas have gained increased attention as the most important fossil resources of energy as well as crude material for petrochemical industries. However, environmental issues such as pollution due to extraction, exploitation and transportation ...
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Background and objectives: Hydrocarbons derived from petroleum and gas have gained increased attention as the most important fossil resources of energy as well as crude material for petrochemical industries. However, environmental issues such as pollution due to extraction, exploitation and transportation of these materials has raised concerns as an environmental warning. In recent years, utilization of biochar (via biomass burning) has been regarded as a soil refiner to reduce or eliminate pollution, especially in in situ studies. Biochar is a product rich in carbon, which is produced during the pyrolysis of various types of woods, fertilizers, leaves, straws as well as agricultural wastes under abiotic conditions. It seems that biochar can be suggested as a suitable compound to manage biomass wastes as well as to enhance soil fertility. Thus, kinetic behavior of biochar in reduction of gasoil pollution of soil, its changes of this pollutant over time and changes in the microbial activity in this time period were investigated.Materials and methods: The soil polluted with gasoil was collected from the vicinity of the gasoil tanker located in Shiraz refinery. The soil had been polluted for years due to the leakage of gasoil. Then, after the measurement of the initial total petroleum hydrocarbon content and physical and chemical properties (soil texture via hydrometry, electrical conductivity in the saturated paste, available phosphorous using the Olsen method, total nitrogen using the Kjehdahl method, pH of soil in the saturated paste, soil carbon using the Walkey and Black method) of the polluted soil, 700 gram soil samples containing wheat straw biochar at one and two mm sizes and 20, 40, 60, 80 and 100 g kg-1 weight doses were prepared as split-split-plot experiment based on a completely randomized design with three replicates. The samples were then rested in a 50% constant humidity for four weeks at 28 ± 2 °C, and were aerated two times a week. Finally, the results of the changes in the total petroleum hydrocarbon and microbial activity over time were recorded. A three- parameter sigmoidal function was fitted to the data related to the total petroleum hydrocarbon and microbial activity over time. Analysis of variance was carried out using the SAS software v. 9.0. The leas significant difference method (LSD) was used to compare the means. The changes in the total petroleum hydrocarbons and microbial activity were analyzed using the SigmaPlot software v. 12.5. Microsoft Excel v. 2013 and SigmaPlot v. 12.5 were used to draw the figures. Results: According to the results of the present study, the application of biochar had a significant effect on the reduction of gasoil pollution of the soil. The results related to determination of the kinetic model for the reduction of pollution during the biochar application process showed that the kinetic of reduction in total petroleum hydrocarbon was of first order equation; so that in the first 28 days of the experiment, the rate of total petroleum hydrocarbon degradation was increasing, whereas it decreased 35 days after the beginning of the experiment. Biodegradation constant (k) was higher for the soil treated with the refiner and these soils had a lower half-life compared with the polluted control. The rate of reduction in half-life and Biodegradation constant rate increased with increasing refiner weight. On the contrary, half-life increased and Biodegradation constant decreased with increasing refiner size. The results indicated a significant difference in the traits as a result of applying various sizes and weights of refiner. Weekly monitoring of the pollution degradation and bioremediation performance in all refiner sizes and weights showed that the lowest time to 50% pollutant removal was obtained in 100g kg-1 and 1 mm size treatment. Investigation of the respiration under the mentioned conditions showed that the lower sizes and higher weights of biochar led to improved hydrocarbon degradation. Also, according to the results, biological efficiency (E%) of biochar was calculated 40.05 at the end of the 60 day period.Conclusion: According to the present study, biochar refiner has a great potential for utilization as a cheap and relatively new strategy to eradicate or reduce soil hydrocarbon pollution. This method is compatible with the in situ bioremediation in the soils polluted with petroleum and other petroleum derivate compounds, due to being less costly and posing less hydrocarbon threat to the environment. It is also a suitable tool to devise bioremediation strategies.
Soil Physics, Erosion and Conservation
Sahar Akhavan; Soheila Ebrahimi; Maryam Navabian; Mahmoud Shabanpour; Alireza Movahedi; Ali Mojtahedi
Abstract
Introduction Soil macropores are the prominent factor in the transfer of wastewater, fertilizers, and microorganisms, including fecal bacteria to deeper soils and even underground waters. On the other hand, a vast majority of land in Iran is located in arid and semi-arid regions. Therefore, the use of ...
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Introduction Soil macropores are the prominent factor in the transfer of wastewater, fertilizers, and microorganisms, including fecal bacteria to deeper soils and even underground waters. On the other hand, a vast majority of land in Iran is located in arid and semi-arid regions. Therefore, the use of salty and unconventional waters has recently gained considerable importance. The aim of this study is to investigate the preferential transportation and storage of Escherichia coli (as an important bacterium in commonly used fertilizers) under the condition of saline water application. Materials and methods The laboratory studies were conducted in a preferential flow system with artificial macropores with different diameters (1 and 2 cm) and varying salinity treatments (1, 2 and 4 dsm-1) under a saturated flow condition. The leaching test was performed at 20°C within several phases. Microbial transfer tests were carried out in two phases with boundary conditions and flow velocities similar to the zero-phase condition. In order to evaluate the bacteria in the soil profile, after the end of the bacterial transfer test, the soil column was divided and cut into 3 layers. Two samples were collected from 3 depths and at macropore and matrix zones. The experiment was conducted in a factorial format and completely randomized design with three replications. The results showed that the mutual effect of salinity and macropore diameter was significant (at 5%) on mean output concentration (Cav), soil filtration coefficient (fλ), relative absorption index (SR), and maximal predicted depth of bacteria transfer (Zmax). Results The results indicated that the bacteria were affected by the treatments during the transfer, so that with increasing the salinity and reducing the diameter of macropores, the average bacterial concentration output decreased. The presence of macropores and the integrity of pores in a column with a diameter of 2 cm accelerated the bacterial movement and increased the pollutant outflow index due to high porosity; therefore, more bacteria passed (compared to the control column without macropores). The salinity treatment, however, served as an inhibitor and hindered further transmission of bacteria. Moreover, The macropore-free column with a salinity of 4 dsm-1 exhibited a higher refining coefficient (0.85 cfuml-1) compared to other treatments. A salinity treatment involving a 1 dsm-1 salinity and a pore diameter of 2 cm showed the least filtration coefficient (0.82 cfuml-1), so by doubling the ionic strength, 30% reduction can be seen in the bacterial filtration coefficient. Increasing the salinity up to 2 dsm-1 and decreasing the macropores diameter increased the relative absorption index. The macropore-free treatment with a 2 dsm-1 salinity showed the highest relative sorption index (0.92). Although the bacterial growth and mortality are unknown during the bacterial transfer process, according to the results, it is expected that the bacterial mortality rate increases by the salinity enhancement from 2 to 4 dsm-1 and the relative adsorption index reduction which may result in lower surface sorption. The significant treatment for the maximum predicted depth of bacterial transfer was the mutual effect of salinity and diameter at a probability level of 5%, which confirmed the significant impact of salinity on the bacterial filtration and transfer. The maximum depth of predicted bacterial transfer was obtained in the macropore-free treatment with the salinity of 1 dsm-1 (16.81 cm). The role of the underlying layers in the bacterial refinery seems to be more profound compared to the surface layer. Conclusion Overall, the results showed that the main source of transmission of bacteria is the preferential flow due to the macropore continuity. However, the salinity reduced the amount of bacterial refining by increasing the ionic strength of the soil solution. The salinity had a significant effect on the average output bacterial concentration, bacterial refining coefficient, relative sorption index, and maximum predicted bacterial transmission depth. The results of this study revealed that increased ionic strength of soil solution can enhance the bacterial refining and the further elimination of bacteria which can be effective in controlling the pollution of underground water by saline irrigation management. Regarding the quantitatively and qualitatively critical water status in the country, conditions can be provided for the use of unconventional water sources, without threatening the environment and contaminating the underground water.
Soil Physics, Erosion and Conservation
Motahareh Noorzade Roshan; Reza Ghorbani Nasrabadi
Abstract
Introduction Soil quality has been defined as a “The potential of soil to play a positive relationship with the other parts of ecosystem”. Soil biological indicators provide insight into the living component of the soil. Similar to physical and chemical indicators, biological indicators have ...
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Introduction Soil quality has been defined as a “The potential of soil to play a positive relationship with the other parts of ecosystem”. Soil biological indicators provide insight into the living component of the soil. Similar to physical and chemical indicators, biological indicators have a relationship to soil functions and can evaluate soil functions to assess soil quality. Between biological indicators, an index that can be measured quickly and easily is more useful to show the changes. In many studies an indicator of microbial respiration, microbial population, nitrogen mineralization and enzymes activity can be used. Special ability is required to measure quickly and show the quality of soil microorganisms and reaction to environmental changes. Soil health is defined by chemical and physical parameters such as soil texture, soil pH, electrical conductivity, etc., that are not quantifiable completely. Therefore, conservation practices planting and forestry may directly or indirectly affect a organism’s activities. The results of land-use systems without consideration of the consequences on soil quality have been environmental degradation. Agricultural management systems have been generally adopted without attending to soil conservation and soil quality, and this therefore causes significant decline in agricultural soil health worldwide. Different methods of soil conservation have been proposed to prevent erosion and improve soil quality destructive phenomena. In Golestan province due to topographical and climatic conditions and less soil sensitivity to erosion, more attention should be given to this issue. But it remains unclear how far this conservation practice can take to prevent damage. This study aimed to investigate the role of conservative practices to improve the soil quality indicators.Materials and Methods The watershed of Chehelchai is located between North latitudes 36° 59´ and 37° 13´ and Earth longitudes 55° 23´ and 55° 38´. The history of land use in the region shows that more than about 40 years ago, all the study area was covered by forest. Agricultural land use changes occurred on a large scale. With emphasis on conservation operation, parts of the agricultural land were changed to productive gardens, partly forested, partly pasture with native species. Different land uses were selected in loess formations, and slope of 41 %, with life operations was about 6 to 7 years. Protective Operations Garden species, terraces and forestry were selected and quality of soil was compared with agricultural land, pasture and natural forest. In this regard, 10 soil samples were taken. After preparation of the samples, physical, chemical and biological analysis were measured. Additionally, soil properties (pH, Electrical Conductivity, Calcium carbonate, organic matter, texture, bulk density, aggregate stability, microbial respiration, microbial biomass population count of micro- arthropods, biological soil quality) were analyzed. The data were analyzed using software SAS. Ver 9. and the results were compared in a randomized complete block design. Analysis of variance in the form of randomized complete block design was done using the LSD multiple comparison. Results and Discussion Our results showed that the dominant soil texture class in land uses was silty loam. It seems that soil texture is less affected by the land use changes. The results showed that the changes of forest and pasture to agricultural lands have destroyed the soil quality. Soil quality indicators such as organic matter and aggregate stability have declined by 60 and 70 percent respectively. Like wise, biological indicators such as microbial respiration, microbial biomass carbon and QBS (biological soil quality indicators based on the population of micro- arthropods) and EMI (index dependence of soil to soil organisms) showed a similar trend. In contrast, the Conservation practices improved the indices. Biological indicators in the forestry and gardening showed an increase of 40 percent in EMI Microbial biomass carbon and 80 percent in microbial respiration. Terracing had less improvement than other operations in about 11 to 20 percent in EMI and microbial biomass carbon. Conclusion Conservation operations had fewer effects on indicators such as aggregate stability and organic matter. Under estimation of effects in certain indicators maybe due to short time of conservation practices. It seems that these operations will show better results in the future Received: 19 July, 2016Accepted: 10 April, 2018
